A Surprising Solid-Phase Effect: Development of a Recyclable "Traceless" Linker System for Reactions on Solid Support
Triazenes as “traceless” linkers for solid‐phase synthesis have been utilized for the attachment of arenes to a solid support and yield the corresponding products after various organometallic reactions (Heck reaction and asymmetric dihydroxylation, see the reaction scheme) and cycloadditions (Diels–...
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| Published in | Angewandte Chemie (International ed.) Vol. 37; no. 24; pp. 3413 - 3415 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
WILEY-VCH Verlag GmbH
31.12.1998
WILEY‐VCH Verlag GmbH Wiley |
| Subjects | |
| Online Access | Get full text |
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| Abstract | Triazenes as “traceless” linkers for solid‐phase synthesis have been utilized for the attachment of arenes to a solid support and yield the corresponding products after various organometallic reactions (Heck reaction and asymmetric dihydroxylation, see the reaction scheme) and cycloadditions (Diels–Alder reaction). The triazene linker is distinguished by its accessibility, thermal robustness, and capability to undergo regeneration. |
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| AbstractList | Triazenes as "traceless" linkers for solid-phase synthesis have been utilized for the attachment of arenes to a solid support and yield the corresponding products after various organometallic reactions (Heck reaction and asymmetric dihydroxylation, see the reaction scheme) and cycloadditions (Diels-Alder reaction). The triazene linker is distinguished by its accessibility, thermal robustness, and capability to undergo regeneration. |
| Author | Enders, Dieter Köbberling, Johannes Avemaria, Frank Bräse, Stefan |
| Author_xml | – sequence: 1 givenname: Stefan surname: Bräse fullname: Bräse, Stefan email: braese@oc.rwth-aachen.de organization: Institut für Organische Chemie der Technischen Hochschule, Professor-Pirlet-Strasse 1, D-52074 Aachen (Germany), Fax: (+49) 241-8888127 – sequence: 2 givenname: Dieter surname: Enders fullname: Enders, Dieter organization: Institut für Organische Chemie der Technischen Hochschule, Professor-Pirlet-Strasse 1, D-52074 Aachen (Germany), Fax: (+49) 241-8888127 – sequence: 3 givenname: Johannes surname: Köbberling fullname: Köbberling, Johannes organization: Institut für Organische Chemie der Technischen Hochschule, Professor-Pirlet-Strasse 1, D-52074 Aachen (Germany), Fax: (+49) 241-8888127 – sequence: 4 givenname: Frank surname: Avemaria fullname: Avemaria, Frank organization: Institut für Organische Chemie der Technischen Hochschule, Professor-Pirlet-Strasse 1, D-52074 Aachen (Germany), Fax: (+49) 241-8888127 |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/29711298$$D View this record in MEDLINE/PubMed |
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| Keywords | C-C coupling ORGANIC-SYNTHESIS RESIN CLEAVAGE solid-phase synthesis STRATEGIES LINKING asymmetric synthesis arenes AMINES ASYMMETRIC DIHYDROXYLATION triazenes BOND DERIVATIVES METATHESIS Arenes Asymmetric synthesis Solid-phase synthesis Triazenes |
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THE REDUCTION OF DIAZONIUM SALTS BY PHOSPHOROUS ACID publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY contributor: fullname: KORNBLUM, N – volume: 53 start-page: 5643 year: 1997 ident: WOS:A1997WV23900002 article-title: Solid-phase organic reactions .2. A review of the literature Nov 95 Nov 96. publication-title: TETRAHEDRON contributor: fullname: Hermkens, PHH – volume: 58 start-page: 1144 year: 1980 ident: WOS:A1980KB45100014 article-title: THE USE OF POLYMER SUPPORTS IN ORGANIC-SYNTHESIS .22. REGIOSELECTIVITY IN CYCLOADDITION REACTIONS ON SOLID-PHASES publication-title: CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE contributor: fullname: YEDIDIA, V – volume: 110 start-page: 1187 year: 1998 ident: WOS:000078039500023.43 publication-title: ANGEW CHEM contributor: fullname: SAUERBREI B |
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| Snippet | Triazenes as “traceless” linkers for solid‐phase synthesis have been utilized for the attachment of arenes to a solid support and yield the corresponding... Triazenes as "traceless" linkers for solid-phase synthesis have been utilized for the attachment of arenes to a solid support and yield the corresponding... |
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| SubjectTerms | Arenes Asymmetric synthesis C-C coupling Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology Solid-phase synthesis Triazenes |
| Title | A Surprising Solid-Phase Effect: Development of a Recyclable "Traceless" Linker System for Reactions on Solid Support |
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