A Surprising Solid-Phase Effect: Development of a Recyclable "Traceless" Linker System for Reactions on Solid Support

Triazenes as “traceless” linkers for solid‐phase synthesis have been utilized for the attachment of arenes to a solid support and yield the corresponding products after various organometallic reactions (Heck reaction and asymmetric dihydroxylation, see the reaction scheme) and cycloadditions (Diels–...

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Published inAngewandte Chemie (International ed.) Vol. 37; no. 24; pp. 3413 - 3415
Main Authors Bräse, Stefan, Enders, Dieter, Köbberling, Johannes, Avemaria, Frank
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag GmbH 31.12.1998
WILEY‐VCH Verlag GmbH
Wiley
Subjects
Arenes
Asymmetric synthesis
C-C coupling
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
Solid-phase synthesis
Triazenes
C-C coupling
ORGANIC-SYNTHESIS
RESIN
CLEAVAGE
solid-phase synthesis
STRATEGIES
LINKING
asymmetric synthesis
arenes
AMINES
ASYMMETRIC DIHYDROXYLATION
triazenes
BOND
DERIVATIVES
METATHESIS
Arenes
Asymmetric synthesis
Solid-phase synthesis
Triazenes
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Summary:Triazenes as “traceless” linkers for solid‐phase synthesis have been utilized for the attachment of arenes to a solid support and yield the corresponding products after various organometallic reactions (Heck reaction and asymmetric dihydroxylation, see the reaction scheme) and cycloadditions (Diels–Alder reaction). The triazene linker is distinguished by its accessibility, thermal robustness, and capability to undergo regeneration.
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ISSN:1433-7851
1521-3773
DOI:10.1002/(SICI)1521-3773(19981231)37:24<3413::AID-ANIE3413>3.0.CO;2-K