Stimuli-Responsive Semi-Fluorinated Polymer Brushes on Porous Silica Substrates

• Published in: Macromolecular rapid communications. Vol. 25; no. 14; pp. 1298 - 1302
• Main Authors: Granville, Anthony M., Brittain, William J.
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag 21.07.2004; WILEY‐VCH Verlag; Wiley
• Subjects: Applied sciences; atom transfer radical polymerization (ATRP); Copolymerization; Exact sciences and technology; Organic polymers; Physicochemistry of polymers; polymer brushes; Preparation, kinetics, thermodynamics, mechanism and catalysts; stimuli-sensitive polymers; Alkyl acrylate copolymer; Fluorine containing copolymer; Methyl acrylate copolymer; Atom transfer polymerization; Polymer brush; Experimental study; Porous material; Silica; Interface structure; Medium effect; Preparation; Diblock copolymer; Graft polymers
• ISSN: 1022-1336; 1521-3927
• DOI: 10.1002/marc.200400193

A diblock copolymer brush consisting of poly(methyl acrylate)‐block‐poly(pentafluoropropyl acrylate) (Si/SiO2//PMA‐b‐PPFA) was synthesized on a porous silica substrate. The brush was exposed to selective solvents, as well as thermal treatments, to induce a surface rearrangement. The rearrangement resulted in the selective loss or creation of an ultrahydrophobic layer by location of the fluoropolymer segment. This work demonstrates that surface rearrangements observed on flat surfaces can be transferred to porous substrates. Image of a water droplet in contact with an Si/SiO2//PMA‐b‐PPFA ultrahydrophobic polymer brush, synthesized from a porous silica substrate.