Isolation and Structure of the OCNCO+ Ion

Strongly bent at the nitrogen atom (130.7°), the OCNCO+ ion (see structure) is the closest relative to carbon suboxide OCCCO. According to calculations the linear OCNCO+ ion is only a few kJ mol−1 higher in energy.

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Bibliographic Details
Published inAngewandte Chemie International Edition Vol. 38; no. 15; pp. 2232 - 2233
Main Authors Bernhardi, Ingrid, Drews, Thomas, Seppelt, Konrad
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag GmbH 02.08.1999
WILEY‐VCH Verlag GmbH
Subjects
Cumulenes
Structure elucidation
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Summary:Strongly bent at the nitrogen atom (130.7°), the OCNCO+ ion (see structure) is the closest relative to carbon suboxide OCCCO. According to calculations the linear OCNCO+ ion is only a few kJ mol−1 higher in energy.
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ark:/67375/WNG-M446XWV3-R
ArticleID:ANIE2232
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ObjectType-Feature-2
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ISSN:1433-7851
1521-3773
DOI:10.1002/(SICI)1521-3773(19990802)38:15<2232::AID-ANIE2232>3.0.CO;2-2