Determination of rare earth elements in waters by inductively coupled plasma optical emission spectrometry after preconcentration with 6-(2-thienyl)-2-pyridinecarboxaldehyde functionalized Amberlite XAD-4 resin

• Published in: Water science and technology Vol. 69; no. 2; pp. 312 - 319
• Main Authors: KARADAS, Cennet, KARA, Derya
• Format: Journal Article
• Language: English
• Published: London International Water Association 2014; IWA Publishing
• Subjects: Amberlite (trademark); Applied sciences; Detection; Detection limits; Dysprosium; Earth; Elution; Emission; Emissions; Erbium; Exact sciences and technology; Flow rates; Inductively coupled plasma; Metals, Rare Earth - chemistry; Neodymium; pH effects; Plasma; Pollution; Polystyrenes - chemistry; Polyvinyls - chemistry; Rare earth elements; Resins, Synthetic - chemistry; Scientific imaging; Spectrometry; Spectroscopy; Trace elements; Water - chemistry; Water analysis; Water sampling; Water treatment and pollution; Ytterbium; waters; Lanthanide; 6-(2-thienyl)-2-pyridinecarboxaldehyde; Amberlite XAD-4; preconcentration; Emission; inductively coupled plasma optical emission spectrometry (ICP-OES); Heavy metal; Blood plasma; Trace element; Spectrometry; Ion exchange resin; rare earth elements (REEs)
• ISSN: 0273-1223; 1996-9732
• DOI: 10.2166/wst.2013.712

A new method has been developed for the determination of rare earth elements (REEs) (Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu) in water samples based on preconcentration with a mini-column packed with 6-(2-thienyl)-2-pyridinecarboxaldehyde functionalized Amberlite XAD-4 resin prior to their determination using inductively coupled plasma optical emission spectrometry (ICP-OES). The optimum experimental parameters for preconcentration of REEs, such as pH of the sample, sample and eluent flow rates and sample volume, were investigated. The optimum pH values for quantitative (90-110%) sorption of the REE ions were between 6.0 and 8.0. The elution process was carried out using 2 mL of 1.0 mol L(-1) HNO3 solution. Under the optimum conditions, detection limits between 0.032 and 0.963 μg L(-1) for a 10 mL sample volume and 0.006 and 0.193 μg L(-1) for a 50 mL sample volume were determined. The proposed method was successfully applied to the determination of REEs in water samples with recoveries in the range of 90.1-110.5%.