Hydrosilylation catalysis by an earth alkaline metal silyl: synthesis, characterization, and reactivity of bis(triphenylsilyl)calcium

Bis(triphenylsilyl)calcium [Ca(SiPh3)(2)(thf)] obtained in high yield as a crystalline ether adduct catalyzes the hydrosilylation of activated C-C double bonds efficiently and regioselectively.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 50; no. 18; pp. 2311 - 2314
Main Authors Leich, Valeri, Spaniol, Thomas P., Maron, Laurent, Okuda, Jun
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2014
Royal Society of Chemistry
Subjects
Carbon-carbon composites
Catalysis
Chemical bonds
Chemical Physics
Chemistry
Chemistry, Multidisciplinary
Crystal structure
Earth
Ethers
Hydrosilylation
Physical Sciences
Physics
Science & Technology
Synthesis (chemistry)
1,1-DIPHENYLETHYLENE
ORGANOMETALLIC COMPOUNDS
SOLUBLE CALCIUM HYDRIDE
PYRIDINE
COMPLEXES
SILICON
ANIONIC CATALYSTS
HOMOGENEOUS CATALYSIS
LIGAND
BUTYL-LITHIUM
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Summary:Bis(triphenylsilyl)calcium [Ca(SiPh3)(2)(thf)] obtained in high yield as a crystalline ether adduct catalyzes the hydrosilylation of activated C-C double bonds efficiently and regioselectively.
Bibliography:ObjectType-Article-1
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ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc49308c