On-line preconcentration and determination of trace elements in waters and reference cereal materials by flow injection – FAAS using newly synthesized 8-hydroxy-2-quinoline carboxaldehyde functionalized Amberlite XAD-4

• Published in: Journal of food composition and analysis Vol. 32; no. 1; pp. 90 - 98
• Main Authors: Karadaş, Cennet, Kara, Derya
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier Inc 01.11.2013; Elsevier
• Subjects: 8-Hydroxy-2-quinoline carboxaldehyde; Amberlite XAD-4; Biological and medical sciences; cadmium; cobalt; copper; detection limit; Flame atomic absorption spectrometry (FAAS); Food analysis; Food composition; Food industries; Food safety; Fundamental and applied biological sciences. Psychology; General aspects; Heavy metal contamination in food; hydrodynamics; infrared spectroscopy; lead; Limit of detection; LOD; manganese; Matrix interference effect; metal ions; Methods of analysis, processing and quality control, regulation, standards; nickel; nitric acid; On-line preconcentration; sorption; Trace elements; Water analysis; LOD; Heavy metal contamination in food; Amberlite XAD-4; 8-Hydroxy-2-quinoline carboxaldehyde; Matrix interference effect; On-line preconcentration; Food analysis; Limit of detection; Water analysis; Food safety; Trace elements; Food composition; Flame atomic absorption spectrometry (FAAS); Water; On line; Amberlite; Material flow; Detection limit; Preconcentration; Quinoline; Food; Flow injection; Interference; Matrix effect; Contamination; Flame spectrometry; Heavy metal; Trace element; Analysis; Reference material; Cereal; Atomic absorption spectrometry
• ISSN: 0889-1575; 1096-0481
• DOI: 10.1016/j.jfca.2013.07.003

•A new polymeric resin was synthesized.•The resin was used for the enrichment of heavy metals in waters and cereals.•A new on-line flow injection preconcentration method was developed using FAAS.•Limits of detections were quite low at sub ppb levels for most of the metal ions.•Different water and food samples were efficiently analyzed. A new chelating resin has been developed using Amberlite XAD-4 resin anchored with 8-hydroxy-2-quinoline carboxaldehyde through CN group. The synthesized resin, characterized by infrared spectroscopy, was used as packing for the minicolumn in an on-line preconcentration system for cadmium, cobalt, copper, lead, manganese and nickel (Cd, Co Cu, Pb, Mn and Ni) determination. Metal ions retained on the modified resin were eluted using 1.0molL−1 HNO3 solution and aspirated directly to the nebulizer–burner system of a FAAS instrument using a flow injection system. Optimum hydrodynamic and chemical conditions for metal sorption were investigated. Detection limits (3σ) were determined to be 0.14μgL−1 for Cd, 0.35μgL−1 for Cu, 0.26μgL−1 for Mn, 0.70μgL−1 for Co, 0.72μgL−1 for Ni and 2.92μgL−1 for Pb using a 10mL sample loading. Enrichment factors for Cu(II), Mn(II), Co(II), Pb(II), Ni(II) and Cd(II) were found to be 22.3, 24.7, 23.2, 24.1, 20.2 and 27.6, respectively. The proposed method was successfully applied to the determination of analytes in water samples, and in food samples such as cereal certified reference materials.