Improved calcium sulfate recovery from a reverse osmosis retentate using eutectic freeze crystallization

• Published in: Water science and technology Vol. 67; no. 1; pp. 139 - 146
• Main Authors: RANDALL, D. G, MOHAMED, R, NATHOO, J, ROSSENRODE, H, LEWIS, A. E
• Format: Journal Article
• Language: English
• Published: London International Water Association 01.01.2013; IWA Publishing
• Subjects: Applied sciences; Calcium; Calcium sulfate; Calcium Sulfate - chemistry; Crystallization; Drinking water and swimming-pool water. Desalination; Eutectic temperature; Exact sciences and technology; Feasibility studies; Freezing; Low temperature; Osmosis; Pollution; Recovery; Reverse osmosis; Rivers; Salts; Scaling; Sulfates; Thermodynamics; Waste Disposal, Fluid - methods; Water - chemistry; Water Purification - methods; Water reuse; Water treatment and pollution; Yield; Membrane separation; Sulfur compounds; Water treatment; environment; separations; Desalination; Crystallization; eutectic freeze crystallization; Reverse osmosis; calcium sulfate; Sulfates
• ISSN: 0273-1223; 1996-9732
• DOI: 10.2166/wst.2012.540

A novel low temperature crystallization process called eutectic freeze crystallization (EFC) can produce both salt(s) and ice from a reverse osmosis (RO) stream by operating at the eutectic temperature of a solution. The EFC reject stream, which is de-supersaturated with respect to the scaling component, can subsequently be recycled back to the RO process for increased water recovery. This paper looks at the feasibility of using EFC to remove calcium sulfate from an RO retentate stream and compares the results to recovery rates at 0 and 20 °C. The results showed that there was a greater yield of calcium sulfate obtained at 0 °C as compared with 20 °C. Operation under eutectic conditions, with only a 20% ice recovery, resulted in an even greater yield of calcium sulfate (48%) when compared with yields obtained at operating temperatures of 0 and 20 °C (15% at 0 °C and 13% at 20 °C). The theoretical calcium recoveries were found to be 75 and 70% at 0 and 20 °C respectively which was higher than the experimentally determined values. The EFC process has the added advantage of producing water along with a salt.