[(C9H7)YbI(DME)2], the First Indenyl Half-Sandwich Complex of Divalent Ytterbium
The reaction of the naphthalene ytterbium(II) complex (µ‐C10H8)[YbI(DME)2]2 (1) with indene proved to be a convenient synthetic route to the novel indenyl half‐sandwich ytterbium(II) complex [(C9H7)YbI(DME)2] (2), which is a monomer in the solid state and stable in DME solution, although it rearrang...
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Published in | European journal of inorganic chemistry Vol. 2001; no. 12; pp. 3055 - 3058 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
Weinheim
WILEY-VCH Verlag GmbH
01.12.2001
WILEY‐VCH Verlag GmbH |
Subjects | |
Online Access | Get full text |
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Summary: | The reaction of the naphthalene ytterbium(II) complex (µ‐C10H8)[YbI(DME)2]2 (1) with indene proved to be a convenient synthetic route to the novel indenyl half‐sandwich ytterbium(II) complex [(C9H7)YbI(DME)2] (2), which is a monomer in the solid state and stable in DME solution, although it rearranges in THF to give the symmetric derivatives [(C9H7)2Yb(THF)2] and [YbI2(THF)2]. The reaction of 2 with equimolar amounts of C5H5Na in DME yields [(C5H5)2Yb(DME)] and [(C9H7)2Yb(DME)]. |
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Bibliography: | ark:/67375/WNG-9Q7VJG2H-0 istex:6CDC1C6FB7C7A931689EED9971B88DFC17292889 ArticleID:EJIC3055 |
ISSN: | 1434-1948 1099-0682 |
DOI: | 10.1002/1099-0682(200112)2001:12<3055::AID-EJIC3055>3.0.CO;2-M |