Rhodium‐Catalyzed Synthesis of Dialkyl(Heteroaryl)Phosphine Sulfides by Phosphinylation of Heteroaryl Sulfides

Dialkyl(heteroaryl)phosphine sulfides were synthesized by the rhodium‐catalyzed exchange reaction of heteroaryl aryl sulfides and tetraalkyldiphosphine disulfides. The reaction has a broad applicability, giving diverse dialkyl(heteroaryl)phosphine sulfides containing five‐ and six‐membered heteroary...

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Bibliographic Details
Published inAdvanced synthesis & catalysis Vol. 360; no. 18; pp. 3488 - 3491
Main Authors Arisawa, Mieko, Tazawa, Takeru, Ichinose, Wataru, Kobayashi, Haruki, Yamaguchi, Masahiko
Format Journal Article
LanguageEnglish
Published WEINHEIM Wiley 17.09.2018
Wiley Subscription Services, Inc
Subjects
Aromatic compounds
Chemical synthesis
Chemistry
Chemistry, Applied
Chemistry, Organic
desulfurization
dialkyl(heteroaryl)phosphine sulfides
Phosphines
phosphinylation
Physical Sciences
Rh catalysis
Rhodium
Science & Technology
Sulfides
tetraalkyldiphosphine disulfides
PHOSPHONIUM IONIC LIQUIDS
DIARYLPHOSPHINE OXIDES
ROOM-TEMPERATURE
COMPLEXES
DIPHENYLPHOSPHINE
tetraalkyldiphosphine disulfides
DIRECT PHOSPHORYLATION
Rh catalysis
desulfurization
HETEROCYCLES
dialkyl(heteroaryl)phosphine sulfides
DERIVATIVES
phosphinylation
METAL-FREE
ARYL CHLORIDES
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Summary:Dialkyl(heteroaryl)phosphine sulfides were synthesized by the rhodium‐catalyzed exchange reaction of heteroaryl aryl sulfides and tetraalkyldiphosphine disulfides. The reaction has a broad applicability, giving diverse dialkyl(heteroaryl)phosphine sulfides containing five‐ and six‐membered heteroaryl groups. Various dialkyl(heteroaryl)phosphines were obtained by desulfurization.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201800630