The marriage of endo-cavity and exo-wall complexation provides a facile strategy for supramolecular polymerization

Butylated pillar[5]arene (1) and N , N ′-bis( n -butyl)pyromellitic diimide (2) form a 2 : 1 sandwich-type complex external to the walls of the receptor (“exo-wall” complex). The marriage of exo-wall interactions and endo-cavity inclusion provides a new strategy for the construction of supramolecula...

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 51; no. 16; pp. 3434 - 3437
Main Authors Wang, Shilu, Wang, Yiliang, Chen, Zhenxia, Lin, Yuejian, Weng, Linhong, Han, Kang, Li, Jian, Jia, Xueshun, Li, Chunju
Format Journal Article
LanguageEnglish
Published England 25.02.2015
Subjects
aromatic hydrocarbons
Complexation
Construction
Diimide
Inclusions
Polymerization
polymers
Receptors
Strategy
Walls
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Summary:Butylated pillar[5]arene (1) and N , N ′-bis( n -butyl)pyromellitic diimide (2) form a 2 : 1 sandwich-type complex external to the walls of the receptor (“exo-wall” complex). The marriage of exo-wall interactions and endo-cavity inclusion provides a new strategy for the construction of supramolecular polymers from unfunctionalized neutral receptors.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/C4CC08820D