Electrochemically conductive treatment of TiO2 nanotube arrays in AlCl3 aqueous solution for supercapacitors

• Published in: Journal of power sources Vol. 294; pp. 216 - 222
• Main Authors: Zhong, Wenjie, Sang, Shangbin, Liu, Yingying, Wu, Qiumei, Liu, Kaiyu, Liu, Hongtao
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 30.10.2015
• Subjects: Al-doped TiO2; Cathodic polarization; Supercapacitor; Cathodic polarization; Supercapacitor; Al-doped TiO2
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2015.06.052

Highly ordered TiO2 nanotube arrays (NTAs) with excellent stability and large specific surface area make them competitive using as supercapacitor materials. Improving the conductivity of TiO2 is of great concern for the construction of high-performance supercapacitors. In this work, we developed a novel approach to improve the performance of TiO2 materials, involving the fabrication of Al-doped TiO2 NTAs by a simple electrochemical cathodic polarization treatment in AlCl3 aqueous solution. The prepared Al-doped TiO2 NTAs exhibited excellent electrochemical performances, attributing to the remarkably improved electrical conductivity (i.e., from approx. 10 kΩ to 20 Ω). Further analysis showed that Al3+ ions rather than H+ protons doped into TiO2 lattice cause this high conductivity. A MnO2/Al–TiO2 composite was evaluated by cyclic voltammetry, and achieved the specific capacitance of 544 F g−1, and the Ragone plot of the sample showed a high power density but less reduction of energy density. These results indicate that the MnO2/Al–TiO2 NTAs sample could be served as a promising electrode material for high -performance supercapacitors. •we report a mild electrochemical method to form Al-doped TiO2 nanotube arrays (NTAs).•Al-doped TiO2 NTAs show a highest electrical conductivity of approx. 20 Ω.•The elemental composition of Al-doped TiO2 NTAs were studied by XPS analysis.•Al-doped TiO2 were proved to be excellent supports materials for supercapacitors.