Castor oil as potential multifunctional additive in the formulation of eco-friendly lubricant

• Published in: Polymer bulletin (Berlin, Germany) Vol. 75; no. 2; pp. 501 - 514
• Main Authors: Ghosh, Pranab, Hoque, Mainul, Karmakar, Gobinda
• Format: Journal Article
• Language: English
• Published: Berlin/Heidelberg Springer Berlin Heidelberg 01.02.2018; Springer Nature B.V
• Subjects: Additives; Antiwear additives; Azobisisobutyronitrile; Castor oil; Characterization and Evaluation of Materials; Chemistry; Chemistry and Materials Science; Complex Fluids and Microfluidics; Copolymers; Fatty acids; Gel chromatography; Infrared spectroscopy; Kinematics; Lubricants; Lubricants & lubrication; Mineral oils; Molecular weight; NMR spectroscopy; Organic Chemistry; Original Paper; Performance evaluation; Physical Chemistry; Polymer Sciences; Polymerization; Polymers; Soft and Granular Matter; Soil testing; Spectral methods; Stability analysis; Thermal stability; Thermogravimetric analysis; Toxicity; Vegetable oils; Viscosity; Mumbai India; India; Free radical polymerization; Antiwear; Viscosity index improver; Pour point depressant; Castor oil; Biodegradability
• ISSN: 0170-0839; 1436-2449
• DOI: 10.1007/s00289-017-2047-6

The article investigates the performance of polymers prepared from castor oil and dodecyl acrylate as biodegradable multifunctional additive in the formulation of eco-friendly lubricant. Homopolymer of castor oil and its copolymers with dodecyl acrylate (DA) at different percentage ratios (w/w) were synthesized using azobisisobutyronitrile (AIBN) as initiator without any solvent. The polymers were characterized by spectral techniques (FT-IR and NMR spectroscopy). The molecular weight of all the prepared polymers was determined by gel permeation chromatography (GPC). The thermal stability of the polymers was determined by thermogravimetric analysis (TGA). Performance evaluation of all the prepared polymers in SN150 mineral oil as viscosity index improver (VII), pour point depressant (PPD) and antiwear were carried out according to standard ASTM methods. The action mechanism of the additives as PPD was studied by photo micrographic image. Biodegradability of all the samples was tested through soil burial test (SBT).