Correlation between coordinated water content and proton conductivity in Ca–BTC-based metal–organic frameworks

Proton conductivity of five Ca-based MOFs which depends on the amount of water molecules coordinated to the Ca-centres has been reported. These MOFs show high temperature proton conductivity due to the strong hydrogen bonding between the lattice and coordinated water molecules.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 48; no. 70; pp. 8829 - 8831
Main Authors Mallick, Arijit, Kundu, Tanay, Banerjee, Rahul
Format Journal Article
LanguageEnglish
Published England 01.01.2012
Subjects
chemical communication
chemical reactions
coordination polymers
Correlation
Hydrogen bonding
Lattices
Metal-organic frameworks
Moisture content
temperature
water content
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Summary:Proton conductivity of five Ca-based MOFs which depends on the amount of water molecules coordinated to the Ca-centres has been reported. These MOFs show high temperature proton conductivity due to the strong hydrogen bonding between the lattice and coordinated water molecules.
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ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/c2cc34006b