Nickel-catalyzed and benzoic acid-promoted direct sulfenylation of unactivated arenes

A nickel-catalyzed and benzoic acid-promoted direct sulfenylation of unactivated arenes using removable 2-(pyridine-2-yl)-isopropylamine as a directing group is described. This strategy provides an efficient access to valuable aryl sulfides with ample substrate scope and a high degree of functional...

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Published inChemical communications (Cambridge, England) Vol. 51; no. 17; pp. 3582 - 3585
Main Authors Yang, Ke, Wang, Yuqi, Chen, Xinyong, Kadi, Adnan A., Fun, Hoong-Kun, Sun, Hao, Zhang, Yan, Lu, Hongjian
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 28.02.2015
Subjects
amines
Aromatic compounds
aromatic hydrocarbons
Benzene Derivatives - chemistry
Benzoic Acid - chemistry
Catalysis
catalytic activity
chemical reactions
Chemistry
Chemistry, Multidisciplinary
Functional groups
moieties
Molecular Structure
Nickel
Nickel - chemistry
organic sulfur compounds
Physical Sciences
Science & Technology
Strategy
Substrates
Sulfides
Sulfides - chemical synthesis
Sulfides - chemistry
Tolerances
FUNCTIONALIZATION
C(SP)-H BONDS
ACTIVATION
C-H BOND
COUPLING REACTIONS
ARYL HALIDES
ARYLATION
COPPER
DIRECT THIOLATION
EFFICIENT
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Summary:A nickel-catalyzed and benzoic acid-promoted direct sulfenylation of unactivated arenes using removable 2-(pyridine-2-yl)-isopropylamine as a directing group is described. This strategy provides an efficient access to valuable aryl sulfides with ample substrate scope and a high degree of functional group tolerance.
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ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/C4CC10431E