Synthesis, structure, and electrochemical properties of new ''unsymmetrical'' metal dithiolate complexes

New ''unsymmetrical'' (mixed ligand) metal dithiolate complexes, expected as components of molecular conductors, have been obtained by a ligand-exchange reaction in refluxing acetone, followed by isolation with a preparative HPLC (ODP; acetonitrile-H2O). Their electrochemical dat...

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Bibliographic Details
Published inChemistry letters no. 9; pp. 921 - 922
Main Authors Kato, R, Kashimura, Y, Sawa, H, Okano, Y
Format Journal Article
LanguageEnglish
Published TOKYO Chemical Soc Japan 01.09.1997
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
CRYSTAL-STRUCTURES
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Summary:New ''unsymmetrical'' (mixed ligand) metal dithiolate complexes, expected as components of molecular conductors, have been obtained by a ligand-exchange reaction in refluxing acetone, followed by isolation with a preparative HPLC (ODP; acetonitrile-H2O). Their electrochemical data suggest that the acceptor (donor) ability and the on-site Coulomb energy for the ''unsymmetrical'' complexes can be tuned by a combination of ligands.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.1997.921