Applications of Danishefsky’s dienes in asymmetric Oxo-Diels-Alder reactions

[Display omitted] Applications of Danishefsky’s dienes in catalytic asymmetric hetero-Diels-Alder (AHDA) reactions or specifically, their asymmetric Oxo-Diels-Alder (AOxo-DA) reactions with appropriate dienophiles are highlighted in detail, including the preparation of catalysts with discussion from...

Full description

Saved in:
Bibliographic Details
Published inTetrahedron: asymmetry Vol. 28; no. 11; pp. 1506 - 1556
Main Authors Taheri kal Koshvandi, Afsaneh, Heravi, Majid M.
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 15.11.2017
Subjects
TADDOL
BINOL
TBME
(−)-CHIRAPHOS
EDOT
TBS
PMB
CAB
BNP
TBAT
DABNTf
TBDPS
TMSF
TFA
CAN
TON
Phebox
PEG
5-C1-BIPOL
DPENTf
(−)-DIOP
DMF
Ti(OiPr)4
Online AccessGet full text

Cover

More Information
Summary:[Display omitted] Applications of Danishefsky’s dienes in catalytic asymmetric hetero-Diels-Alder (AHDA) reactions or specifically, their asymmetric Oxo-Diels-Alder (AOxo-DA) reactions with appropriate dienophiles are highlighted in detail, including the preparation of catalysts with discussion from a mechanistic points of view. Danishefsky’s dienes are effective and useful compounds for the synthesis of optically active six-membered rings such as dihydropyrones, dihydropyridones and dihydropyrans. Due to the broad range of the overall subject, we have limited ourselves, to the recent developments in the utility of Danishefsky’s dienes in the reaction with carbonyl compounds (aldehydes, ketones and 1,2-dicarbonyl compounds) in asymmetric Oxo-Diels-Alder (AOxo-DA) reactions.
ISSN:0957-4166
1362-511X
DOI:10.1016/j.tetasy.2017.10.030