Densifying hydration products of alite by a bio-inspired admixture

[Display omitted] •Tannic acid (TA) can be used to mediate the hydration of tricalcium silicate (alite) to achieve better microstructure.•TA can form complex with calcium ion through chelating, thus retarding the hydration of the alite.•TA can promote the growth of calcium hydroxide along x-axis.•TA...

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Bibliographic Details
Published inMaterials & design Vol. 225; p. 111490
Main Authors Fang, Yi, Wang, Jialai, Wang, Liang, Qian, Xin, Wang, Xiaodong, Liao, Wenyu, Chen, Peiyuan, Ma, Hongyan
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.01.2023
Elsevier
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Summary:[Display omitted] •Tannic acid (TA) can be used to mediate the hydration of tricalcium silicate (alite) to achieve better microstructure.•TA can form complex with calcium ion through chelating, thus retarding the hydration of the alite.•TA can promote the growth of calcium hydroxide along x-axis.•TA can modify the atomic structure of calcium silicate hydrate.•TA has a unique ability to radically reduce inter-hydrate pores of cement paste. A bio-inspired, plant-derived polyphenol, tannic acid (TA) was identified as a renewable admixture to improve the compressive strength of concretes. Aiming to understand the underlying mechanism responsible for this strength improvement, this study examines how TA mediates the hydration of tricalcium silicate (alite). Experimental study shows that TA can form complex with calcium ions through chelating, retarding the hydration of the alite and changing of the hydration products. Particularly, X-ray diffraction analysis shows that TA makes calcium hydroxide preferentially grow on the [001] face. Fourier-transform infrared spectroscopy and 29Si MAS NMR results reveal that the mean chain length of calcium silicate hydrate (CSH) is reduced by TA. More importantly, mercury intrusion porosimetry testing reveals that pores with size near 30 nm was almost eliminated by adding TA, leading to higher elastic modulus of the produced CSH and higher compressive strength of the produced concrete.
ISSN:0264-1275
1873-4197
DOI:10.1016/j.matdes.2022.111490