Ag2S nanoparticles decorated graphene as a selective chemical sensor for acetone working at room temperature

• Published in: Applied surface science Vol. 562; p. 150201
• Main Authors: Jang, A-Rang, Lim, Ji Eun, Jang, Seunghun, Kang, Myung Hyun, Lee, Geonhee, Chang, Hyunju, Kim, EunKyoung, Park, Joung Kyu, Lee, Jeong-O.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.10.2021
• Subjects: Acetone; Ag2S; Chemical sensor; Graphene; Ultrasonic irradiation; Ag2S; Chemical sensor; Ultrasonic irradiation; Graphene; Acetone
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2021.150201

[Display omitted] •Sensitivity of graphene-based chemical sensors can be improved with nanoparticles decorations.•Ag2S nanoparticles-decorated graphene exhibited ~660% increase in response to acetone.•DFT calculations showed higher binding energies between Ag2S and small-chain ketones. Decorating graphene with nanoparticles is an effective method for improving gas selectivity and sensitivity of graphene-based chemical sensors. We report herein the enhancement of the gas selectivity and improved response of a graphene-based chemical sensor by decorating the graphene with synthesized Ag2S nanoparticles. To synthesize uniformly sized Ag2S nanoparticles, we used the ultrasonic irradiation method, and then the synthesized Ag2S nanoparticles were decorated onto graphene uniformly, by using a simple spin coating method. Gas responses of the resulting chemical sensor were tested for volatile organic compounds (VOCs) such as acetone, ethanol, and hexane. While no noticeable gas response changes were obtained for ethanol and hexane vapors, a dramatic increase of ~660% resulted from exposure of the sensor to acetone vapor. In order to determine the mechanism behind the excellent acetone response of graphene decorated with Ag2S nanoparticles, density functional theory (DFT) calculations were performed, and showed higher binding energies and electron transfer between Ag2S and acetone than between Ag2S and the other VOCs. This result indicated that decorating graphene with nanoparticles displaying a high binding energy for the target gas is an efficient way to improve the gas selectivity and response levels of graphene-based chemical sensors.