UV-light-assisted preparation of MoO3−x/Ag NPs film and investigation on the SERS performance

• Published in: Journal of materials science Vol. 55; no. 21; pp. 8868 - 8880
• Main Authors: Niu, Zhiqiang, Zhou, Canliang, Wang, Jiawei, Xu, Yinghao, Gu, Chenjie, Jiang, Tao, Zeng, Shuwen, Zhang, Yonghui, Ang, Diing Shenp, Zhou, Jun
• Format: Journal Article
• Language: English
• Published: New York Springer US 01.07.2020; Springer Nature B.V
• Subjects: Characterization and Evaluation of Materials; Chemical Routes to Materials; Chemistry and Materials Science; Classical Mechanics; Crystallography and Scattering Methods; experimental design; Gold; Materials Science; Metal nitrides; Metal oxides; Molybdenum oxides; Molybdenum trioxide; Multilayers; Nanoparticles; nanosilver; nitrides; Noble metals; oxides; Polymer Sciences; Raman spectra; Raman spectroscopy; Reducing agents; Rhodamine; rhodamines; silicon; Silicon substrates; Silver; silver nitrate; Solid Mechanics; Spectrum analysis; Spin coating; Transition metals; Ultraviolet radiation
• ISSN: 0022-2461; 1573-4803
• DOI: 10.1007/s10853-020-04669-5

Surface-enhanced Raman scattering (SERS) technique is a powerful spectrum analysis technique for the ultra-low molecular trace detection. Conventionally, noble metals like silver (Ag) and gold (Au) are used to prepare the SERS substrates; however, limitations of complicated experimental designs and sophisticated process steps impede their wide applications in practice. Recently, metal oxides arise as a promising material for SERS application, but relatively weak Raman signal enhancement and poor material stability still pose as a challenge. Here, a UV-light-assisted fabrication of MoO 3− x /silver nanoparticles (MoO 3− x /Ag NPs) film is proposed. In the experiment, the sub-transition-metal-oxide of MoO 3− x was used as the Raman chemical enhancement substrate as well as the reducing agent. Through the spin-coating of MoO 3− x layer on the silicon substrate and UV-light-assisted reduction of silver nitride (AgNO 3 ) on the MoO 3− x layer, a novel MoO 3− x /Ag NPs one-layer film was fabricated. Using the Rhodamine B (RhB) as the Raman reporter, SERS measurement shows that enhancement factor (EF) of 1.195 × 10 6 could be achieved. Moreover, a Raman signal amplifying strategy is further demonstrated by constructing MoO 3− x /Ag NPs multi-layer films. And result evidences that maximum gain of 2.07 for the RhB Raman peak at 1280 cm −1 can be obtained on the MoO 3− x /Ag NPs three-layer film when referred to that on the MoO 3− x /Ag NPs one-layer film. Meanwhile, the EF of the MoO 3− x /Ag NPs three-layer film is also improved to 2.985 × 10 6 , giving the minimum detectable concentration of 10 −9 M.