Ultrafiltration of Divalent Metal Cations from Aqueous Solution Using Polycarboxylic Acid Type Biosurfactant

• Published in: Journal of colloid and interface science Vol. 202; no. 1; pp. 63 - 73
• Main Authors: Hong, Jeong-Jin, Yang, Seung-Man, Lee, Choul-Ho, Choi, Young-Kook, Kajiuchi, Toshio
• Format: Journal Article
• Language: English
• Published: San Diego, CA Elsevier Inc 01.06.1998; Elsevier
• Subjects: Applied sciences; biosurfactant-based ultrafiltration; Chemical engineering; divalent metal ions; Exact sciences and technology; Membrane separation (reverse osmosis, dialysis...); micelle; precipitation; spiculisporic acid; micelle; precipitation; biosurfactant-based ultrafiltration; divalent metal ions; spiculisporic acid; Divalent metal Ions; Nickel II Ions; Zinc II Ions; Polymeric membranes; Cadmium II Ions; Micelle; Experimental study; Mass transfer; Fungi; Rejection; Sodium Compounds; Membrane separation; Anionic surfactant; Transition metal Ions; Ultrafiltration; Microbial origin; Penicillium spiculisporum; Fungi Imperfecti; Aqueous solution; Cellulose acetate; Performance; Copper II Ions; Thallophyta; Tricarboxylic acid
• ISSN: 0021-9797; 1095-7103
• DOI: 10.1006/jcis.1998.5446

Biosurfactant-based ultrafiltration was used to remove the divalent metal ions, Cu+2, Zn+2, Cd+2, and Ni+2ions from aqueous solution containing either a single metal species or a mixtures of metal ions. Polycarboxylic acid type biosurfactant, sodium salt of 2-(2-carboxyethyl)-3-decyl maleic anhydride (DCMA-3Na) derived from spiculisporic acid was added to trap the metal ions through the binding onto the micelles and/or the formation of metal-biosurfactant precipitates. The present study aimed at investigating the permeating flux and the removal efficiencies of divalent metal cations from aqueous solutions using a batch-type stirred ultrafiltration cell. Concerning the flux decline, the membrane of molecular weight cutoff (MWCO) 1,000 is more vulnerable to the formation of a gel layer and the concentration polarization than that of MWCO 3,000. Formation of metal-biosurfactant precipitates makes the gel concentration of DCMA-3Na relatively low compared with the case of chemically synthesized surfactant such as SDS and CPC. However, biosurfactant-based ultrafiltration is of practical significance because high rejection efficiencies for cupric, zinc, cadmium ions can be achieved only with equimolar ratio of DCMA-3Na to the metal ions. DCMA-3Na exhibits the metal binding affinity on the order of Cd+2> Cu+2≈ Zn+2> Ni+2when one metal species is present. Even under the competitive binding condition when four metal ions are present in the mixture, DCMA-3Na shows the same affinity order toward the metal ions, although small variations in rejection coefficients are observed.