Blue light-promoted photolysis of aryldiazoacetates

Aryldiazoacetates can undergo photolysis under blue light irradiation (460-490 nm) at room temperature and under air in the presence of numerous trapping agents, such as styrene, carboxylic acids, amines, alkanes and arenes, thus providing a straighforward and general platform for their mild functio...

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Bibliographic Details
Published inChemical science (Cambridge) Vol. 9; no. 22; pp. 5112 - 5118
Main Authors Jurberg, Igor D., Davies, Huw M. L.
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 2018
Royal Society of Chemistry
Subjects
Alkanes
Amines
Aromatic compounds
Carboxylic acids
Chemistry
Chemistry, Multidisciplinary
Light irradiation
Photolysis
Physical Sciences
Science & Technology
ALPHA-DIAZOCARBONYL COMPOUNDS
VISIBLE-LIGHT
DONOR/ACCEPTOR CARBENES
CYCLOADDITION REACTIONS
CHEMICAL BIOLOGY
ASYMMETRIC CYCLOPROPANATION
DIAZO-COMPOUNDS
STEREOSELECTIVE FUNCTIONALIZATION
N-H INSERTION
CATALYZED INTRAMOLECULAR CYCLOPROPANATION
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Summary:Aryldiazoacetates can undergo photolysis under blue light irradiation (460-490 nm) at room temperature and under air in the presence of numerous trapping agents, such as styrene, carboxylic acids, amines, alkanes and arenes, thus providing a straighforward and general platform for their mild functionalization.
Bibliography:FAPESP
National Science Foundation
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:2041-6520
2041-6539
DOI:10.1039/c8sc01165f