Pillar-layered MOFs: functionality, interpenetration, flexibility and applications
Pillar-layered metal-organic frameworks (MOFs) are among the most interesting research areas in crystalline materials. Due to the great number of reports related to pillar-layered MOFs, investigating their structural diversity, properties and applicability as multi-donor porous frameworks is of grea...
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| Published in | Journal of materials chemistry. A, Materials for energy and sustainability Vol. 6; no. 4; pp. 19288 - 19329 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
Cambridge
Royal Society of Chemistry
2018
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| Subjects | |
| Online Access | Get full text |
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| Summary: | Pillar-layered metal-organic frameworks (MOFs) are among the most interesting research areas in crystalline materials. Due to the great number of reports related to pillar-layered MOFs, investigating their structural diversity, properties and applicability as multi-donor porous frameworks is of great interest. Modifying pillar moieties as a third building block of pillar-layered MOFs, together with metal nodes and oxygen donor linkers, can enhance control of the structure assembly, leading to specific properties of the obtained structures. Although the past decade has witnessed remarkable advances in this research area, pillar-layered MOFs have not been reviewed as an independent subject to date. Therefore, a review summarizing their performance is greatly needed. This review covers issues related to pillar-layered MOFs, including their structural properties, synthesis, stability, diversity of linkers, and improved applicability. Finally, pillar linkers are studied separately according to their diverse donor atoms and functional groups.
Pillar-layered metal-organic frameworks (MOFs) are among the most interesting research areas in crystalline materials. |
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| Bibliography: | Farnoosh ZareKarizi was born and raised in Tehran, Iran. She received her B.S. degree in 2012 from Shahid Beheshti University, Tehran. Then, she attended Tarbiat Modares University, Tehran and obtained her M.S. degree in inorganic chemistry. She is now a Ph.D. student at Tarbiat Modares University under the guidance of Prof. Ali Morsali. Her research interests are inorganic chemistry and metal-organic frameworks. Monika Joharian was born and raised in Karaj, Iran. She received her B.S. degree from Razi University, Kermanshah. Then, she attended the Chemistry & Chemical Engineering Research Center of Iran, Tehran, where she obtained her M.S. degree in inorganic chemistry. She is now a Ph.D. student at Tarbiat Modares University under the guidance of Prof. Ali Morsali. Her research interests are inorganic chemistry, catalysis and metal-organic frameworks. Ali Morsali was born and raised in the Hidaj, Zanjan, Iran. He attended Tarbiat Moallem University, Tehran and earned a B.S. degree in Pure Chemistry. He received his Inorganic Chemistry in Zanjan University, Zanjan. He then attended graduate school at the University of Tarbiat Modares, Tehran and earned his Ph.D. under the guidance of Prof. Ali Reza Mahjoub. After completing his Ph.D., he began his independent career at the University of Tarbiat Modares, Tehran, where he is a Professor in the Department of Chemistry. In 2016, he passed six months as a sabbatical period in Prof. Hupp and Prof. Farha group, Northwestern University. He also passed the other six months as a sabbatical period in Prof. Omar Yaghi group, Berkeley in 2017. His research interests are primarily in the area of inorganic chemistry, coordination polymers and metal-organic frameworks. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23 |
| ISSN: | 2050-7488 2050-7496 2050-7496 |
| DOI: | 10.1039/c8ta03306d |