Graphene quantum dot engineered ultrathin loose polyamide nanofilms for high-performance nanofiltration

• Published in: Journal of materials chemistry. A, Materials for energy and sustainability Vol. 8; no. 45; pp. 2393 - 23938
• Main Authors: Li, Yafei, You, Xinda, Li, Ya, Yuan, Jinqiu, Shen, Jianliang, Zhang, Runnan, Wu, Hong, Su, Yanlei, Jiang, Zhongyi
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 24.11.2020
• Subjects: Chemical interactions; Diffusion rate; energy; Graphene; Membranes; Nanofiltration; nanosheets; Nanotechnology; Piperazine; Polyamide resins; Polyamides; Polymerization; Pore size; Porosity; Quantum dots; Regulators; Reluctance; Selectivity; Sodium sulfate; Thickness; Upper bounds
• ISSN: 2050-7488; 2050-7496; 2050-7496
• DOI: 10.1039/d0ta09319j

Pursuing high water permeance with ultrahigh selectivity is a longstanding objective for nanofiltration membranes. At present, simultaneously engineering an ultrathin thickness and loose architecture of nanofiltration membranes is in great demand and a severe challenge. Herein, we demonstrate a two-in-one strategy toward ultrathin loose polyamide (ULPA) nanofilms via graphene quantum dot (GQD)-mediated support-free interfacial polymerization. Featuring favorable chemical interactions and size, GQDs serve as quasi-molecule-scale regulators to reduce the diffusion rate of piperazine, and generate ULPA nanofilms with a controllable thickness from 18.3 to 5.5 nm. Concomitantly, GQDs are incorporated into ULPA during interfacial polymerization to construct a loose structure, which is manifested by an enlarged pore size. The resultant ULPA composite membranes overcome the upper-bound limit of polyamide membranes, exhibiting a water permeance of 32.1 L m −2 h −1 bar −1 with an ultrahigh Na 2 SO 4 rejection of 99.6%, as well as an unprecedented Cl − /SO 4 2− selectivity of 205.8 that reaches the highest value ever reported. This two-in-one strategy may open a facile avenue to design advanced membranes for environmental and energy relevant applications. Graphene quantum dot-mediated interfacial polymerization generates ultrathin loose polyamide nanofilms for high-performance nanofiltration.