Rhodium-containing oxide-hydrides: covalently stabilized mixed-anion solids

The first rhodium-containing oxide-hydride phases, LaSrCo0.5Rh0.5O3H and La0.5Sr1.5Mn0.5Rh0.5O3H, have been prepared via topochemical anion exchange. This clearly demonstrates the ability of rhodium, a late 4d transition metal, to kinetically stabilize oxide-hydride lattices, reinforcing the paradig...

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Published inChemical communications (Cambridge, England) Vol. 55; no. 33; pp. 4861 - 4864
Main Authors Jin, Lun, Hayward, Michael A
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 18.04.2019
Subjects
Anion exchanging
Hydrides
Lattices
Mixed anions
Rhodium
Transition metal oxides
Transition metals
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Summary:The first rhodium-containing oxide-hydride phases, LaSrCo0.5Rh0.5O3H and La0.5Sr1.5Mn0.5Rh0.5O3H, have been prepared via topochemical anion exchange. This clearly demonstrates the ability of rhodium, a late 4d transition metal, to kinetically stabilize oxide-hydride lattices, reinforcing the paradigm of covalent stabilization of transition-metal oxide-hydride phases.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c9cc01768b