Organic building blocks at inorganic nanomaterial interfaces

• Published in: Materials horizons Vol. 9; no. 1; pp. 61 - 87
• Main Authors: Huang, Yunping, Cohen, Theodore A, Sperry, Breena M, Larson, Helen, Nguyen, Hao A, Homer, Micaela K, Dou, Florence Y, Jacoby, Laura M, Cossairt, Brandi M, Gamelin, Daniel R, Luscombe, Christine K
• Format: Journal Article
• Language: English
• Published: England Royal Society of Chemistry 04.01.2022
• Subjects: Diamonds; Fluorescence; Functional groups; Inorganic materials; Lasers; Lead compounds; Light emitting diodes; Metal halides; Metal oxide semiconductors; Metal oxides; Nanomaterials; Nanostructures; Organic chemistry; Perovskites; Photovoltaic cells; Semiconductors; Silicon
• ISSN: 2051-6347; 2051-6355
• DOI: 10.1039/d1mh01294k

This tutorial review presents our perspective on designing organic molecules for the functionalization of inorganic nanomaterial surfaces, through the model of an anchor-functionality paradigm. This "anchor-functionality" paradigm is a streamlined design strategy developed from a comprehensive range of materials ( e.g. , lead halide perovskites, II-VI semiconductors, III-V semiconductors, metal oxides, diamonds, carbon dots, silicon, etc. ) and applications ( e.g. , light-emitting diodes, photovoltaics, lasers, photonic cavities, photocatalysis, fluorescence imaging, photo dynamic therapy, drug delivery, etc. ). The structure of this organic interface modifier comprises two key components: anchor groups binding to inorganic surfaces and functional groups that optimize their performance in specific applications. To help readers better understand and utilize this approach, the roles of different anchor groups and different functional groups are discussed and explained through their interactions with inorganic materials and external environments. Inorganic-organic interfaces: a tutorial on using organic functional groups to enhance the performances and/or enable new functionality of inorganic nanomaterials.