Synthesis and Supramolecular Association of NCN-Pincer Pd-Complex-bound Norvaline Derivatives toward Fabrication of Controlled Metal Array

Novel NCN-pincer Pd-complex-bound norvaline derivatives were synthesized. The N- and C-termini-alkylated Pd-norvalines spontaneously assemble into fibrous aggregates to form supramolecular gels, in which the NCN-pincer Pd complex moieties assemble in a highly oriented manner.

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Bibliographic Details
Published inChemistry letters Vol. 41; no. 2; pp. 194 - 196
Main Authors Ogata, Kazuki, Sasano, Daisuke, Yokoi, Tomoya, Isozaki, Katsuhiro, Seike, Hirofumi, Yasuda, Nobuhiro, Ogawa, Tetsuya, Kurata, Hiroki, Takaya, Hikaru, Nakamura, Masaharu
Format Journal Article
LanguageEnglish
Published TOKYO Chemical Soc Japan 05.02.2012
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
GELATORS
PEPTIDES
PYRENE
ALPHA-AMINO-ACIDS
ORGANIC LIQUIDS
CATALYST
GELATION
BINDING
CHLORIDE
AMIDES
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Summary:Novel NCN-pincer Pd-complex-bound norvaline derivatives were synthesized. The N- and C-termini-alkylated Pd-norvalines spontaneously assemble into fibrous aggregates to form supramolecular gels, in which the NCN-pincer Pd complex moieties assemble in a highly oriented manner.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2012.194