Alumina-supported MoNx, MoCx and MoPx catalysts for the hydrotreatment of rapeseed oil

• Published in: Applied catalysis. B, Environmental Vol. 263; p. 118328
• Main Authors: Horáček, Jan, Akhmetzyanova, Uliana, Skuhrovcová, Lenka, Tišler, Zdeněk, de Paz Carmona, Héctor
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 01.04.2020; Elsevier BV
• Subjects: Aluminum oxide; Brassica napus; Catalysts; Catalytic activity; Deoxygenation; Fixed bed reactors; Fixed beds; Hydrocracking; Hydrotreatment; Mass transfer; Molybdenum; Molybdenum carbide; Molybdenum nitride; Molybdenum phosphide; Oils & fats; Phosphides; Rapeseed; Rapeseed oil; Vegetable oil; Molybdenum nitride; Vegetable oil; Molybdenum phosphide; Molybdenum carbide; Hydrotreatment; Deoxygenation
• ISSN: 0926-3373; 1873-3883
• DOI: 10.1016/j.apcatb.2019.118328

[Display omitted] •Deoxygenation activity during hydrotreatment was in the following order: MoCx > MoNx >> MoPx.•Competitive hydrocracking on MoCx at higher temperatures decreased its deoxygenation activity.•MoNx showed the highest tendency to hydrocracking and very strong effect of WHSV at 350 °C.•Activity of MoPx was considerably affected by mass transfer limitations. The catalytic activity of molybdenum carbide (MoCx), nitride (MoNx), and phosphide (MoPx) was compared in the hydrotreatment of rapeseed oil performed in a continuous fixed bed reactor at 350–390 °C, 5.5 MPa and various Weight Hourly Space Velocities (WHSV). The deoxygenation activity was in the following order: MoCx > MoNx >> MoPx. In the case of MoCx, the temperature increase resulted in a decrease of the deoxygenation activity due to the competitive hydrocracking. Wherein, MoNx showed the highest tendency to hydrocracking and very strong effect of WHSV at 350 °C, which then became less significant at higher reaction temperatures. While MoPx activity was strongly influenced by the mass transfer limitations.