Thermoinduced structural-transformation and thermochromic luminescence in organic manganese chloride crystals

The [Mn Cl ] mode of red emissive (C NOH ) Mn Cl ·C H OH under thermal treatment will be cleaved into [MnCl ] in the green emissive (C NOH ) MnCl with the departure of ethanol. The rapid conversion of luminescence from red to green provides new insight into the luminescence origin and thermal stabil...

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Published inChemical science (Cambridge) Vol. 10; no. 13; pp. 3836 - 3839
Main Authors Sun, Meng-En, Li, Yao, Dong, Xi-Yan, Zang, Shuang-Quan
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 07.04.2019
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Summary:The [Mn Cl ] mode of red emissive (C NOH ) Mn Cl ·C H OH under thermal treatment will be cleaved into [MnCl ] in the green emissive (C NOH ) MnCl with the departure of ethanol. The rapid conversion of luminescence from red to green provides new insight into the luminescence origin and thermal stability of organic-inorganic metal halide hybrids.
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ISSN:2041-6520
2041-6539
DOI:10.1039/c8sc04711a