Between single ion magnets and macromolecules: a polymer/transition metal-based semi-solid solution

• Published in: Chemical science (Cambridge) Vol. 9; no. 36; pp. 7277 - 7286
• Main Authors: Majcher, Anna M, Dąbczyński, Paweł, Marzec, Mateusz M, Ceglarska, Magdalena, Rysz, Jakub, Bernasik, Andrzej, Ohkoshi, Shin-Ichi, Stefańczyk, Olaf
• Format: Journal Article
• Language: English
• Published: England Royal Society of Chemistry 2018
• Subjects: Cobalt; Crosslinking; Crystallography; Dilution; Ellipsometry; Forming; Fourier transforms; Ions; Macromolecules; Magnetic induction; Magnetic materials; Magnetic permeability; Magnetic relaxation; Magnetism; Magnets; Polymers; Secondary ion mass spectroscopy; Semisolids; Solid solutions; Spectrum analysis; Spintronics; Thin films; X ray photoelectron spectroscopy
• ISSN: 2041-6520; 2041-6539
• DOI: 10.1039/c8sc02277a

The creation of functional magnetic materials for application in high-density memory storage or in the new field of molecular spintronics is a matter of widespread interest among the material research community. Herein, we describe a new approach that combines the qualities of single ion magnets, displaying slow magnetic relaxations, and the merits of polymers, being easy to process and widely used to produce thin films. Basing the idea on cobalt(ii) ions and pyridine-based single ion magnets, a new macromolecular magnetic material was obtained - a polymeric matrix of poly(4-vinylpyridine) (P4VP) cross-linked by a cobalt(ii) salt bound within it, effectively forming a network of single ion magnets, with field-induced magnetic relaxations preserved in both bulk and thin film forms. The binding of cobalt is confirmed by a series of methods, like secondary ion mass spectroscopy or high-resolution X-ray photoelectron spectroscopy. The magnetic relaxation times, up to 5 × 10 s, are controllable simply by dilution, making this new material a semi-solid solution. By this approach, a new path is formed to connect molecular magnetism and polymer science, showing that the easy polymer processing can be used in forming self-organizing functional magnetic thin films.