N-(5-Benzyl-sulfanyl-1,3,4-thia-diazol-2-yl)-2-(piperidin-1-yl)acetamide

The title compound, C16H20N4OS2, was synthesized by the reaction of 2-benzyl-sulfanyl-5-chloro-acetamido-1,3,4-thia-diazole and piperidine in a 1:2 ratio. The planes of the acetamide and 1,3,4-thia-diazole units are twisted by 10.8 (4)°. The thia-diazole S atom and the acetamide O atom are syn-orien...

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Published inActa crystallographica. Section E, Structure reports online Vol. 70; no. Pt 3; p. o241
Main Authors Ismailova, D S, Okmanov, R Ya, Ziyaev, A A, Shakhidoyatov, Kh M, Tashkhodjaev, B
Format Journal Article
LanguageEnglish
Published United States International Union of Crystallography 01.03.2014
Subjects
Organic Papers
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Summary:The title compound, C16H20N4OS2, was synthesized by the reaction of 2-benzyl-sulfanyl-5-chloro-acetamido-1,3,4-thia-diazole and piperidine in a 1:2 ratio. The planes of the acetamide and 1,3,4-thia-diazole units are twisted by 10.8 (4)°. The thia-diazole S atom and the acetamide O atom are syn-oriented due to a hypervalent S⋯O inter-action of 2.628 (4) Å. In the crystal, mol-ecules form centrosymmetric dimers via N-H⋯N hydrogen bonds. These dimers are further connected by C-H⋯O inter-actions into (100) layers.
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ISSN:1600-5368
1600-5368
DOI:10.1107/S160053681400213X