Reactions and properties of oxo and peroxo derivatives of (pentamethylcyclopentadienyl)-molybdenum and -tungsten
The characterization and reactivity of complexes (η 5-C 5Me 5)M(O)(η 2-O 2)Cl (M = Mo, W) and (η 5-C 5Me 5)M(O)Cl 3 are described. In addition, the preparation and reactivity of some molybdenum-oxo alkyl complexes are discussed in this paper. The oxo-H 2O and oxo-peroxo exchange behavior of these...
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| Published in | Journal of organometallic chemistry Vol. 368; no. 1; pp. 45 - 56 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
23.05.1989
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| Online Access | Get full text |
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| Summary: | The characterization and reactivity of complexes (η
5-C
5Me
5)M(O)(η
2-O
2)Cl (M = Mo, W) and (η
5-C
5Me
5)M(O)Cl
3 are described. In addition, the preparation and reactivity of some molybdenum-oxo alkyl complexes are discussed in this paper. The oxo-H
2O and oxo-peroxo exchange behavior of these systems was studied with infrared spectroscopy using
18O isotope labeling techniques. |
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| ISSN: | 0022-328X 1872-8561 |
| DOI: | 10.1016/0022-328X(89)80117-2 |