Dichlorido(N,N'-diisopropyl-piperidine-1-carboximidamidato-κN,N')titanium(IV)

In the mononuclear title complex, [Ti(C(12)H(24)N(3))(2)Cl(2)], the Ti(IV) ion, located on a crystallographic inversion center, is six-coordinated by four N atoms from two N',N''-diisopropyl-N-carboxamidine anions and two chloride atoms in a distorted octahedral geometry. The dihedral...

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Bibliographic Details
Published inActa crystallographica. Section E, Structure reports online Vol. 67; no. Pt 1; p. m125
Main Authors Wang, Mei, Yao, Ying-Ming, Zhang, Yong, Zhang, Zhen-Qin, Shi, Li-Ying
Format Journal Article
LanguageEnglish
Published United States International Union of Crystallography 01.01.2011
Subjects
Metal-Organic Papers
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Summary:In the mononuclear title complex, [Ti(C(12)H(24)N(3))(2)Cl(2)], the Ti(IV) ion, located on a crystallographic inversion center, is six-coordinated by four N atoms from two N',N''-diisopropyl-N-carboxamidine anions and two chloride atoms in a distorted octahedral geometry. The dihedral angles between the piperidine groups and the NCN chelate rings are 51.5 (1) and 52.3 (1)°.
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ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536810053262