Anticorrosion, Thermal Degradation, and Hydrophobic Performances of Graphene/TiO2 Nanocomposite Coatings

• Published in: Polymers Vol. 15; no. 11; p. 2428
• Main Authors: Kumar, Sachin Sharma Ashok, Mohammed, Nujud Badawi, Alduhaish, Osamah, Ramesh, Kasi, Ramesh, Subramaniam, Khan, Mujeeb, Shaik, Baji, Adil, Syed F
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 23.05.2023; MDPI
• Subjects: Carbon; Chemical bonds; Coatings; Contact angle; Corrosion prevention; Corrosion resistance; Dispersion; Electrochemical analysis; Electrochemical impedance spectroscopy; Electrolytes; Emission analysis; Field emission microscopy; Fourier transforms; Graphene; Heat resistance; High impedance; Infrared analysis; Infrared spectroscopy; Mechanical properties; Nanocomposites; Nanoparticles; Photocatalysis; Pollutants; Polymers; Protective coatings; Surface properties; Thermal degradation; Thermogravimetric analysis; Titanium dioxide; Zinc oxides; electrochemical impedance spectroscopy (EIS); field emission scanning electron microscopy (FESEM); thermogravimetric analysis (TGA); TiO2 nanoparticles; acrylic-epoxy polymer matrix; graphene nanofillers
• ISSN: 2073-4360; 2073-4360
• DOI: 10.3390/polym15112428

Globally, researchers have devoted consistent efforts to producing excellent coating properties since coating plays an essential role in enhancing electrochemical performance and surface quality. In this study, TiO nanoparticles in varying concentrations of 0.5, 1, 2, and 3 wt.% were added into the acrylic-epoxy polymeric matrix with 90:10 wt.% (90A:10E) ratio incorporated with 1 wt.% graphene, to fabricate graphene/TiO2 -based nanocomposite coating systems. Furthermore, the properties of the graphene/TiO2 composites were investigated by Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), ultraviolet-visible (UV-Vis) spectroscopy, water contact angle (WCA) measurements, and cross-hatch test (CHT), respectively. Moreover, the field emission scanning electron microscope (FESEM) and the electrochemical impedance spectroscopy (EIS) tests were conducted to investigate the dispersibility and anticorrosion mechanism of the coatings. The EIS was observed by determining the breakpoint frequencies over a period of 90 days. The results revealed that the TiO2 nanoparticles were successfully decorated on the graphene surface by chemical bonds, which resulted in the graphene/TiO2 nanocomposite coatings exhibiting better dispersibility within the polymeric matrix. The WCA of the graphene/TiO2 coating increased along with the ratio of TiO2 to graphene, achieving the highest CA of 120.85° for 3 wt.% of TiO . Excellent dispersion and uniform distribution of the TiO2 nanoparticles within the polymer matrix were shown up to 2 wt.% of TiO inclusion. Among the coating systems, throughout the immersion time, the graphene/TiO2 (1:1) coating system exhibited the best dispersibility and high impedance modulus values (Z0.01 Hz), exceeding 1010 Ω cm2.