Bis[methyl 2-(2-pyridylmethyl-idene)hydrazinecarbodithio-ato]zinc(II)

In the title compound, [Zn(C(8)H(8)N(3)S(2))(2)], the Zn atom is coordinated by the two ligands in a tridentate manner, via the pyridyl N, the azomethine N and the thiol-ate S atom; the coordination geometry is distorted octa-hedral, with the two ligands in the mer configuration (two S atoms and two...

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Published inActa crystallographica. Section E, Structure reports online Vol. 64; no. Pt 2; pp. m328 - m329
Main Authors Zhou, Xiu-Xia, Zhou, Zheng-Yuan, Chen, Jian-Qiao, Lin, Xiao-Ming, Cai, Yue-Peng
Format Journal Article
LanguageEnglish
Published United States International Union of Crystallography 09.01.2008
Subjects
Metal-Organic Papers
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Summary:In the title compound, [Zn(C(8)H(8)N(3)S(2))(2)], the Zn atom is coordinated by the two ligands in a tridentate manner, via the pyridyl N, the azomethine N and the thiol-ate S atom; the coordination geometry is distorted octa-hedral, with the two ligands in the mer configuration (two S atoms and two pyridyl N atoms are cis with respect to each other and the azomethine N atoms is trans). The mol-ecules are linked by C-H⋯S hydrogen bonds, forming a three-dimensional network structure.
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ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536807068493