Benzene-1,3,5-triyl tris-(methane-sulfonate)

In the mol-ecule of the title compound, C(9)H(12)O(9)S(3), the two methanesulfonate groups re located one above and one below the ring plane. The C-O-S angle range is 119.3 (2)-121.1 (2)°. This conformation is different from that of the benzene analog 1,2,5-tris-(p-toluene-sulfonate), which is a thr...

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Bibliographic Details
Published inActa crystallographica. Section E, Structure reports online Vol. 66; no. Pt 4; p. o739
Main Authors Madrigal, Domingo, Aguirre, Gerardo, Vargas, Berenice
Format Journal Article
LanguageEnglish
Published United States International Union of Crystallography 03.03.2010
Subjects
Organic Papers
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Summary:In the mol-ecule of the title compound, C(9)H(12)O(9)S(3), the two methanesulfonate groups re located one above and one below the ring plane. The C-O-S angle range is 119.3 (2)-121.1 (2)°. This conformation is different from that of the benzene analog 1,2,5-tris-(p-toluene-sulfonate), which is a three-legged 'table' with all fragments of the p-toluene-sulfonate on top of the benzene ring. In the crystal, the supra-molecular aggregation is completed by the presence of C-H⋯O hydrogen bonds.
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ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536810006641