STM Exploration of the Diverse Polymorphs for Tri-Substituted Anthraquinone Derivatives via Alkyl Chain Elongation
Fabrication of structural diversity in self‐assembled monolayers has gained considerable attention, not only due to its significance in interface science but also because of its potential application in designing nanomaterials. Here, systematical characterization of the molecular self‐assembly of tr...
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Published in | Advanced materials interfaces Vol. 3; no. 20; pp. np - n/a |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
Weinheim
Blackwell Publishing Ltd
01.10.2016
John Wiley & Sons, Inc |
Subjects | |
Online Access | Get full text |
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Summary: | Fabrication of structural diversity in self‐assembled monolayers has gained considerable attention, not only due to its significance in interface science but also because of its potential application in designing nanomaterials. Here, systematical characterization of the molecular self‐assembly of tri‐substituted anthraquinone derivatives at the 1‐octanoic acid/HOPG interface is provided. Different nanopatterns of Linear I, Butterfly‐like, and Linear II are recorded for 1,2,4‐A‐3OC16 by gradually changing the solution concentration. Diverse polymorphs are also obtained by alkyl chain elongation, meaning that 1,2,4‐A‐3OC15,17,18 adopt Dimer‐Linear, Linear III, and Linear IV structures, respectively. Dipole–dipole, hydrogen bonding, and van der Waals interactions are the dominant forces on forming the stable adlayers. Also, the coadsorption of the solvent molecules is a common phenomenon, ascribing to space matching and gain of enthalpy. Moreover, the 1,2,4‐A‐3OC17,18 self‐assembled into monolayers consists of both ordered and chaotic domains. This loss of regularity is attributed to the large number and long length of the side chains, for entropy reasons. This work provides important insight into the fabrication of complex molecular self‐assembly and the exploration of monolayers at the liquid/solid interface.
Structural diversity for tri‐substituted anthraquinone has been systematically explored by gradual elongation of the side chains. Hydrogen bonding, van der Waals, and dipole−dipole interactions are proved to be the main driving forces on forming stable monolayers at the liquid/highly oriented pyrolytic graphite interface. It is the first time that the self‐assemblies for anthraquinone derivatives with three side chains have been reported. |
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Bibliography: | Natural Science Foundation of China - No. 21573077; No. 21403072; No. 51373055 ark:/67375/WNG-5XF4CKBQ-5 istex:FD339ABFB6628F827BD0EFF9CE5A901E08C7214E National Program on Key Basic Research Project - No. 2012CB932900 China Postdoctoral Science Foundation - No. 2014M552189 ArticleID:ADMI201600428 ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 2196-7350 2196-7350 |
DOI: | 10.1002/admi.201600428 |