Hydrogen‐Bonded Organic Framework for High‐Performance Lithium/Sodium‐Iodine Organic Batteries

• Published in: Angewandte Chemie International Edition Vol. 61; no. 48; pp. e202213276 - n/a
• Main Authors: Guo, Chaofei, Han, Bo, Sun, Weiwei, Cao, Yingnan, Zhang, Yifan, Wang, Yong
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 25.11.2022
• Edition: International ed. in English
• Subjects: Adsorptivity; Cycles; Encapsulation; Energy demand; Energy storage; Hydrogen; Hydrogen bonding; Hydrogen-Bonded Organic Framework; Iodides; Iodine; Lithium; Lithium/Sodium-Iodine Organic Batteries; Metal ions; Monomers; Nucleation; Reaction kinetics; Reaction mechanisms; Rechargeable batteries; Redox Reaction; Redox reactions; Sodium; Ti3C2Tx MXene
• ISSN: 1433-7851; 1521-3773; 1521-3773
• DOI: 10.1002/anie.202213276

The rechargeable lithium/sodium‐iodine battery (Li/Na‐I2) is a promising candidate for meeting the growing energy demand. Herein, a flexible hydrogen‐bonded organic framework (HOF) linked to the Ti3C2Tx MXene complex (HOF@Ti3C2Tx) has been presented for iodine loading. HOF is self‐assembled by organic monomers through hydrogen bonding interactions between each monomer. It leads to numerous cavities in HOF structure, which can encapsulate iodine through various adsorptive sites and intermolecular interactions. The unique structure of complex can accelerate the nucleation of iodine, achieve fast reaction kinetics, stabilize iodide and retard the shuttle effect, thus improving the cycling stability of I2‐based batteries. The I2/HOF@Ti3C2Tx exhibits large reversible capacities of 260.2 and 207.6 mAh g−1 at 0.2 C after repeated cycling for Li‐I2 and Na‐I2 batteries, respectively. This work can gain insights into the HOF‐related energy storage application with reversible iodine encapsulation and its related redox reaction mechanisms with Li and Na metal ions. A complex of a hydrogen‐bonded organic framework (HOF) linked with Ti3C2Tx MXene was designed and adopted as electrodes with excellent cyclic stability and rate‐performances in Li‐I2 and Na‐I2 batteries.