Synthesis and Fluorescence Properties of Manisyl-Substituted Terpyridine, Bipyridine, and Phenanthroline

As a hybrid of two aryl motifs, that is p‐anisyl and mesityl, the 4‐methoxy‐2,6‐dimethylphenyl or “manisyl” substituent offers possibilities for both further structural elaboration as well as enhancing the solubility of the heterocyclic ligands mentioned in the title. A highlight of this work lies i...

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Bibliographic Details
Published inAngewandte Chemie International Edition Vol. 40; no. 4; pp. 754 - 757
Main Authors Loren, Jon C., Siegel, Jay S.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag GmbH 16.02.2001
WILEY‐VCH Verlag GmbH
Wiley
Subjects
Chemistry
Chemistry, Multidisciplinary
fluorescence
ligand design
N ligands
nitrogen heterocycles
Physical Sciences
Science & Technology
PHOTOLUMINESCENCE
LIGANDS
1,10-PHENANTHROLINES
LUMINESCENCE
BUILDING-BLOCKS
STRATEGY
COMPLEXES
EUROPIUM(III)
SUPRAMOLECULAR CHEMISTRY
DERIVATIVES
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Summary:As a hybrid of two aryl motifs, that is p‐anisyl and mesityl, the 4‐methoxy‐2,6‐dimethylphenyl or “manisyl” substituent offers possibilities for both further structural elaboration as well as enhancing the solubility of the heterocyclic ligands mentioned in the title. A highlight of this work lies in the ability of the manisyl group to endow specific members of this family such as 1 with high fluorescence quantum efficiency.
Bibliography:ArticleID:ANIE7540
istex:FE39B56BCEBDFF223503E60CB4A63B359DED03CA
ark:/67375/WNG-QWRMPLWB-H
Manisyl=4‐methoxy‐2,6‐dimethylphenyl. This work was supported by the US National Science Foundation (CHE‐9904275).
ISSN:1433-7851
1521-3773
DOI:10.1002/1521-3773(20010216)40:4<754::AID-ANIE7540>3.0.CO;2-T