ZnO template strategy for the synthesis of 3D interconnected graphene nanocapsules from coal tar pitch as supercapacitor electrode materials

• Published in: Journal of power sources Vol. 340; pp. 183 - 191
• Main Authors: He, Xiaojun, Li, Xiaojing, Ma, Hao, Han, Jiufeng, Zhang, Hao, Yu, Chang, Xiao, Nan, Qiu, Jieshan
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.02.2017
• Subjects: Aromatic hydrocarbon; Graphene nanocapsule; Nano-ZnO template; Oxygen bridge; Supercapacitor; Supercapacitor; Nano-ZnO template; Oxygen bridge; Aromatic hydrocarbon; Graphene nanocapsule
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2016.11.073

3D interconnected graphene nanocapsules (GNCs) were prepared from diverse aromatic hydrocarbons by a nano-ZnO-template strategy coupled with in-situ KOH activation technique. The as-made graphene networks feature thin carbonaceous shells with well-balanced micropores and mesopores. Such 3D porous networks provide freeways for good electron conduction, short pores for ion fast transport, and abundant micropores for ion adsorption. As the electrodes in supercapacitors, the unique 3D GNCs show a high capacitance of 277 F g−1 at 0.05 A g−1, a good rate performance of 194 F g−1 at 20 A g−1, and an excellent cycle stability with over 97.4% capacitance retention after 15000 cycles in 6 M KOH electrolyte. This synthesis strategy paves a universal way for mass production of 3D graphene materials from diverse aromatic hydrocarbon sources including coal tar pitch and petroleum pitch for high performance supercapacitors as well as support and sorbent. [Display omitted] •Graphene nanocapsules (GNCs) are made by ZnO template via forming oxygen bridges.•GNCs feature 3D interconnected networks and abundant hierarchical short pores.•The GNC electrodes show high capacitance, good rate performance and cycle stability.•This approach provides a novel pathway for mass production of 3D graphene materials.