Lithium and sodium storage in highly ordered mesoporous nitrogen-doped carbons derived from honey

• Published in: Journal of power sources Vol. 335; pp. 20 - 30
• Main Authors: Zhang, Yongzhi, Chen, Li, Meng, Yan, Xie, Jun, Guo, Yong, Xiao, Dan
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 15.12.2016
• Subjects: Anode; Honey; Lithium ion battery; Mesoporous carbon; Nitrogen-doped; Sodium ion battery; Honey; Lithium ion battery; Sodium ion battery; Nitrogen-doped; Anode; Mesoporous carbon
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2016.08.096

Honey, a widely existent biomass, consists mainly of carbohydrate and other nitrogen-containing substances such as proteins, enzymes and organic acids. It can be mixed homogeneously with mesoporous silica template for its excellent water-solubility and moderate viscosity. In this work, honey was employed as a nitrogen-containing carbon precursor to prepare nitrogen-doped ordered mesoporous carbons (OMCs). The obtained honey derived mesoporous nitrogen-doped carbons (HMNCs) with dilated interlayer spacings of 0.387–0.395 nm, narrow pore size distributions centering at around 4 nm and satisfactory N contents of 1.38–4.32 wt% offer superb dual functionality for lithium ion battery (LIB) and sodium ion battery (NIB) anodes. Tested against Li, the optimized HMNC-700 delivers a superior reversible capacity of 1359 mA h g−1 after 10 cycles at 100 mA g−1 and excellent rate capability and cycling stability of 722 mA h g−1 after 200 cycles at 1 A g−1. For NIB applications, HMNC-700 offers a high initial reversible capacity of 427 mA h g−1 and stable reversible capacity of 394 mA h g−1 at 100 mA g−1. A SBA-15 template process was used to prepare honey derived mesoporous nitrogen-doped carbons (HMNCs), which possess narrow pore size distributions centering at around 4 nm and satisfactory N contents, exhibiting excellent lithium and sodium anodic performances. [Display omitted] •Honey is employed as a nitrogen-containing carbon precursor.•A novel highly ordered nitrogen-doped mesoporous carbon is obtained.•The obtained HMNCs exhibit excellent lithium and sodium anodic performance.•The mechanism of Li+/Na+ storage in HMNCs is investigated.