Preparation and characterization of high performance of graphene/nylon nanocomposites

• Published in: European polymer journal Vol. 49; no. 9; pp. 2617 - 2626
• Main Authors: Jin, J., Rafiq, R., Gill, Y.Q., Song, M.
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier Ltd 01.09.2013; Elsevier
• Subjects: Applied sciences; Barrier property; Breaking; Composites; Elongation; Exact sciences and technology; Forms of application and semi-finished materials; Fracture toughness; Graphene; Impact strength; Mechanical property; Nanocomposite; Nanocomposites; Nylon; Nylon 11; Nylons; Polymer industry, paints, wood; Technology of polymers; Ultimate tensile strength; Nanocomposite; Nylon; Barrier property; Graphene; Mechanical property; Mixing; Transport properties; Mechanical properties; Experimental study; Polymer filler interaction; Gas permeability; Amide 11 polymer; Concentration effect; Amide 12 polymer; Manufacturing; Growth from melt
• ISSN: 0014-3057; 1873-1945
• DOI: 10.1016/j.eurpolymj.2013.06.004

Well-dispersed nylon/graphene nanocomposites were prepared successfully. Graphene can improve the toughness and barrier properties of nylons significantly with very low loadings. [Display omitted] •Well-dispersed nylon/graphene nanocomposites were prepared without use of solvents.•Graphene can improve the toughness and impact performance of nylons significantly.•Graphene can reduce water and oxygen permeability of nylons. The potential of using functionalized graphene (FG) as reinforcement for producing high performance of nylons 11 and 12 nanocomposites was explored. A series of FG/nylons 11 and 12 nanocomposites fabricated by a direct melt blending with assistance of pre-mixing was assessed for their mechanical and barrier properties as a function of FG loading. The results revealed that the ultimate tensile strength, elongation at break, impact strength, toughness and permeation resistance characteristics were improved by the incorporation of a very small amount of the FG into the nylon matrices. In the nylon12, the ultimate tensile strength increased by ∼35%, elongation at break by ∼200%, fracture toughness by ∼75% and the impact failure energy by ∼85%, respectively, when only 0.6wt% FG was incorporated. In contrast, the tensile mechanical properties and fracture toughness of the nylon11 was only slightly improved by addition of FG, but a dramatic enhancement of ∼250% in impact strength was achieved by adding 1wt% FG. In addition, the graphene sheets were dramatically effective for improvements of vapor and gas barrier properties for both nylons at a very significant low loading. Especially, the nylon11 films with FG loading as low as 0.3wt% showed a superior to reduction of water vapor and oxygen permeability by ∼49% and ∼47%, respectively. In this communication, the effects of FG on these property enhancements of the nylons have been well discussed. It can be concluded that to achieve the maximally improved properties, aside from good dispersion of the filler, strong interface between the polymer and graphene sheets, flexibility of graphene in the polymer matrix could be considered to be also an important factor due to the characteristics of graphene wrinkled structure in the polymer matrix.