Liquid-liquid extraction of lithium using novel phosphonium ionic liquid as an extractant

• Published in: Hydrometallurgy Vol. 169; pp. 314 - 320
• Main Authors: Shi, Chenglong, Jing, Yan, Xiao, Jiang, Wang, Xingquan, Jia, Yongzhong
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.05.2017
• Subjects: Ionic liquid; Lithium; Solvent extraction; Solvent extraction; Lithium; Ionic liquid
• ISSN: 0304-386X; 1879-1158
• DOI: 10.1016/j.hydromet.2017.02.015

A novel phosphonium ionic liquid (IL), tetrabutylphosphonium bis(2,4,4-trimethylpentyl)phosphinate([P4444][BTMPP]), was prepared and characterized by NMR spectroscopy. The solvent extraction behavior of lithium from aqueous solution by this IL in toluene was investigated. The extraction behavior was carried out as a function of various parameters such as aqueous acidity, temperature and extractant concentration. The extraction efficiencies obtained in [P4444][BTMPP] were compared with those observed in molecular extractant bis(2,4,4-trimethylpentyl) phosphinic acid (HBTMPP), from which the anion of the ionic liquid extractant was prepared. The extraction efficiency for extraction of lithium by [P4444][BTMPP] was much higher than that for extraction by HBTMPP. The extracted species were ascertained from slop analysis method which indicated 1:1 (metal:ligand) ratio in the complex. In addition, the effects of thermodynamic parameters, the stripping of lithium from the ionic liquid, and the reusability of the phosphonium ionic liquid were studied in detail. The phosphonium ionic liquid extractant diluted in toluene is a much better solvent extraction system than the corresponding acidic extractant diluted in toluene. [Display omitted] •Solvent extraction of lithium was investigated using ionic liquid [P4444][BTMPP].•FT-IR spectra of [P4444][BTMPP] were analyzed before/after extraction.•Extraction stoichiometry of Li+ was analyzed by slope analysis method.•Loaded Li(I) could be full stripped using diluted hydrochloric acid.