Rh(II) catalyzed efficient sigmatropic rearrangement reaction of pyridotriazoles and sulfides

• Published in: Green synthesis and catalysis Vol. 5; no. 2; pp. 77 - 79
• Main Authors: Chen, Yuting, Lv, Guanghui, Li, Zhiyang, Ye, Meiling, Huang, Tianle, Hai, Li, Wu, Yong
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.05.2024; KeAi Communications Co. Ltd
• Subjects: [1,2]- Sigmatropic rearrangement; [2,3]-Sigmatropic rearrangement; Pyridotriazole; Rhodium catalysis; Sulfide; Sulfide; Rhodium catalysis; Pyridotriazole; [2,3]-Sigmatropic rearrangement; [1,2]- Sigmatropic rearrangement

The [2,3]- and [1,2]-sigmatropic rearrangement reactions between pyridotriazoles and sulfides catalyzed by rhodium(II) were investigated. The utilization of pyridotriazoles as the carbene precursors in this kind of reaction efficiently constructed the C(sp3)-S and C(sp3)-Se bond with broad substrate...