Rh(II) catalyzed efficient sigmatropic rearrangement reaction of pyridotriazoles and sulfides

The [2,3]- and [1,2]-sigmatropic rearrangement reactions between pyridotriazoles and sulfides catalyzed by rhodium(II) were investigated. The utilization of pyridotriazoles as the carbene precursors in this kind of reaction efficiently constructed the C(sp3)-S and C(sp3)-Se bond with broad substrate...

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Published inGreen synthesis and catalysis Vol. 5; no. 2; pp. 77 - 79
Main Authors Chen, Yuting, Lv, Guanghui, Li, Zhiyang, Ye, Meiling, Huang, Tianle, Hai, Li, Wu, Yong
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.05.2024
KeAi Communications Co. Ltd
Subjects
[1,2]- Sigmatropic rearrangement
[2,3]-Sigmatropic rearrangement
Pyridotriazole
Rhodium catalysis
Sulfide
Sulfide
Rhodium catalysis
Pyridotriazole
[2,3]-Sigmatropic rearrangement
[1,2]- Sigmatropic rearrangement
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Summary:The [2,3]- and [1,2]-sigmatropic rearrangement reactions between pyridotriazoles and sulfides catalyzed by rhodium(II) were investigated. The utilization of pyridotriazoles as the carbene precursors in this kind of reaction efficiently constructed the C(sp3)-S and C(sp3)-Se bond with broad substrate scope and great functional group tolerance. [Display omitted]
ISSN:2666-5549
2666-5549
DOI:10.1016/j.gresc.2023.04.004