Twin-screw extrusion impact on natural fibre morphology and material properties in poly(lactic acid) based biocomposites

• Published in: Industrial crops and products Vol. 46; pp. 173 - 185
• Main Authors: Gamon, G., Evon, Ph, Rigal, L.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.04.2013; Elsevier
• Subjects: Biocomposite; biocomposites; Chemical Sciences; crystal structure; deformation; energy; extrusion; heat; lactic acid; Material chemistry; Mechanical and thermal properties; mechanical properties; natural fibers; Natural fibre; Organic chemistry; Poly(lactic acid); thermal properties; Twin-screw extrusion; viscosity; Natural fibre; Poly(lactic acid); Biocomposite; Mechanical and thermal properties; Twin-screw extrusion; poly (lactic acid)
• ISSN: 0926-6690; 1872-633X
• DOI: 10.1016/j.indcrop.2013.01.026

► Screw speeds and feeding rates were varied during PLA-fibre twin-screw extrusion. ► Higher extrusion parameters saved fibre size without modifying mechanical properties. ► Influence of initial fibre size with four calibrated bamboo grades was studied. ► Composite mechanical properties were enhanced by using the longest fibres. ► Material heat deformation was prevented by using the shortest fibres. Natural fibres from miscanthus and bamboo were added to poly(lactic acid) by twin-screw extrusion. The influence of extruder screw speed and of total feeding rate was studied first on fibre morphology and then on mechanical and thermal properties of injected biocomposites. Increasing the screw speed from 100 to 300rpm such as increasing the feeding rate in the same time up to 40kg/h helped to preserve fibre length. Indeed, if shear rate was increased with higher screw speeds, residence time in the extruder and blend viscosity were reduced. However, such conditions doubled electrical energy spent by produced matter weight without significant effect on material properties. The comparison of four bamboo grades with various fibre sizes enlightened that fibre breakages were more consequent when longer fibres were added in the extruder. Longer fibres were beneficial for material mechanical properties by increasing flexural strength, while short fibres restrained material deformation under heat by promoting crystallinity and hindering more chain mobility.