PVdF-HFP/metal oxide nanocomposites: The matrices for high-conducting, low-leakage porous polymer electrolytes

• Published in: Journal of power sources Vol. 159; no. 1; pp. 295 - 300
• Main Authors: Wu, Chun-Guey, Lu, Ming-I., Tsai, Chung-Chih, Chuang, Huey-Jan
• Format: Journal Article
• Language: English
• Published: Lausanne Elsevier B.V 13.09.2006; Elsevier Sequoia
• Subjects: Applied sciences; Direct energy conversion and energy accumulation; Electrical engineering. Electrical power engineering; Electrical power engineering; Electrochemical conversion: primary and secondary batteries, fuel cells; Exact sciences and technology; Lithium-ion battery; Polymer/inorganic composite; Porous polymer electrolyte; Lithium-ion battery; Porous polymer electrolyte; Polymer/inorganic composite; Scanning electron microscopy; Propylene copolymer; Polymer electrolytes; Secondary cell; Mesoporosity; Lithium battery; Conducting polymers; Pore size; Vinylidene fluoride copolymer; Porosity; Performance; Titanium oxide; Nanostructured materials; Lithium ion; Electrochemical impedance spectroscopy
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2006.04.108

Highly conducting porous polymer electrolytes comprised of poly(vinylidene-fluoride-co-hexafluoropropylene) (PVdF-HFP), metal oxide (TiO 2, MgO, ZnO)/or mesoporous zeolite (MCM-41, SBA-15), ethylene carbonate (EC), propylene carbonate (PC), and LiClO 4 were fabricated with a simple direct evaporation method. It was found that when metal oxide or mesoporous zeolite was mixed with PVdF-HFP, the impedance spectroscopy showed that the room temperature conductivity increased from 1.2 × 10 −3 S cm −1 (for pure PVdF-HFP) to 2.1 × 10 −3 S cm −1. SEM micrographs showed that the pore size of the composite membrane was similar to that of pure PVdF-HFP membrane but the porosity decreased, nevertheless the solution uptake increased. The increasing in solution uptake is not related directly to the surface area or dielectric constant of the oxides. It may be due to the affinity of the metal oxide toward the electrolyte solution. Furthermore, the solution leakage of PVdF-HFP/MgO and PVdF-HFP/SBA-15 composite electrolytes also decreased compared to pure PVdF-HFP electrolyte. These polymer composite electrolytes were stable up to 5.5 V (versus Li/Li +) and the lithium ion cells assembled with these polymer electrolyte show a good performance at a discharge rate below C/2.