Size-Selective Effects on Fullerene Adsorption by Nanoporous Molecular Networks

• Published in: Small (Weinheim an der Bergstrasse, Germany) Vol. 6; no. 1; pp. 76 - 80
• Main Authors: Shen, Yong-Tao, Deng, Ke, Zeng, Qing-Dao, Wang, Chen
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag 04.01.2010; WILEY‐VCH Verlag
• Subjects: Adsorption; Arrays; chirality; Crystallization - methods; Fullerenes; Fullerenes - chemistry; Macromolecular Substances - chemistry; Materials Testing; Molecular Conformation; Nanocomposites; nanoporous materials; Nanostructure; Nanostructures - chemistry; Nanostructures - ultrastructure; Nanotechnology - methods; Networks; Particle Size; Porosity; scanning tunneling microscopy; Surface chemistry; Surface Properties; templates
• ISSN: 1613-6810; 1613-6829; 1613-6829
• DOI: 10.1002/smll.200901601

A new hierarchical self‐assembling molecular template, which can size‐selectively immobilize fullerene molecules, is reported. The molecular template is fabricated from 1,3,5‐tris(10‐carboxydecyloxy)benzene (TCDB) and triangle‐shaped macrocycles. It is observed that the two‐dimensional hydrogen‐bonded achiral TCDB network affected by the 3NN‐Macrocycle becomes a chiral network. Host and guest molecules both form chiral arrangements with hexagonal empty pores. In addition, fullerenes and other molecules such as coronene can be entrapped in the empty pores or on the 3NN‐Macrocycle molecules. The adsorption constant (K) is estimated, from which it is concluded that the different filling behaviors of the fullerenes are associated with the different sizes of the guest species. This method provides a facile approach to molecularly designed surfaces and the study of fullerene molecular arrays on the single‐molecule level. Try it for size: A molecular template is fabricated from 1,3,5‐tris(10‐carboxydecyloxy)benzene (TCDB) and triangular macrocycles to form a chiral network on a graphite substrate (see picture). Host and guest molecules form chiral arrangements with hexagonal empty pores. Coronene and fullerene molecules can be size‐selectively entrapped in the pores or on the macrocycle molecules.