Electrochemical generation of hydrogen peroxide using surface area-enhanced Ti-mesh electrodes

• Published in: Electrochimica acta Vol. 52; no. 22; pp. 6304 - 6309
• Main Authors: Yang, Kyung Shik, Mul, Guido, Moulijn, Jacob A.
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 30.06.2007; Elsevier
• Subjects: Chemistry; Electrochemistry; Electrode; Electrodes: preparations and properties; Electrophoretic deposition; Exact sciences and technology; General and physical chemistry; Hydrogen peroxide; Other electrodes; Oxygen reduction; Ti-mesh; Ti-mesh; Oxygen reduction; Electrode; Hydrogen peroxide; Electrophoretic deposition; Scanning electron microscopy; Oxygen; Transition metal; Surface structure; Electrodes; Chemical reduction; Electrochemical properties; Morphology; Surface properties; Titanium; Surface area; Electrochemical reaction; Modified material
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2007.04.021

Ti-mesh electrodes coated with Ti were obtained by using an electrophoretic deposition (EPD) method. The Ti coating was porous and showed a good adherence to the Ti-mesh surface, due to sintering of Ti particles during thermal treatment at 900 °C. The Ti-coated mesh electrode has a BET surface area of 3.5 m 2/g, about four times larger than that of the bare electrode. The surface area-enhanced Ti-mesh electrode was applied in electrical generation of hydrogen peroxide. It was shown that the rate of hydrogen peroxide generation increased drastically compared to the fresh electrode, since the larger electrode surface area enhanced not only current density, but also the oxygen mass transfer rate.