New insight into adsorption characteristics and mechanisms of the biosorbent from waste activated sludge for heavy metals

• Published in: Journal of environmental sciences (China) Vol. 45; no. 7; pp. 248 - 256
• Main Authors: Zhou, Yun, Zhang, Zhiqiang, Zhang, Jiao, Xia, Siqing
• Format: Journal Article
• Language: English
• Published: Netherlands Elsevier B.V 01.07.2016
• Subjects: Adsorption; Biosorbent; Kinetics; Metal ions; Metals, Heavy - chemistry; Models, Chemical; Pb2; Response surface methodology (RSM); Sewage - chemistry; Temperature; Waste activated sludge; X射线光电子能谱分析; 原子力显微镜分析; 吸附机理; 生物吸附剂; 重金属污泥; 金属离子; 静电相互作用; Biosorbent; Waste activated sludge; Adsorption; Response surface methodology (RSM); Metal ions
• ISSN: 1001-0742; 1878-7320
• DOI: 10.1016/j.jes.2016.03.007

The adsorption characteristics and mechanisms of the biosorbent from waste activated sludge were investigated by adsorbing Pb2＋and Zn2＋in aqueous single-metal solutions. A p H value of the metal solutions at 6.0 was beneficial to the high adsorption quantity of the biosorbent. The optimal mass ratio of the biosorbent to metal ions was found to be 2. A higher adsorption quantity of the biosorbent was achieved by keeping the reaction temperature below 55°C. Response surface methodology was applied to optimize the biosorption processes, and the developed mathematical equations showed high determination coefficients（above 0.99 for both metal ions） and insignificant lack of fit（p = 0.0838 and 0.0782 for Pb2＋and Zn2＋, respectively）. Atomic force microscopy analyses suggested that the metal elements were adsorbed onto the biosorbent surface via electrostatic interaction. X-ray photoelectron spectroscopy analyses indicated the presence of complexation（between –NH2,-CN and metal ions） and ion-exchange（between –COOH and metal ions）. The adsorption mechanisms could be the combined action of electrostatic interaction, complexation and ion-exchange between functional groups and metal ions.